Sustainable H2 generation via steam reforming of biogas in membrane reactors: H2S effects on membrane performance and catalytic activity

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چکیده

This study proposes the steam reforming of a synthetic biogas stream containing 200 ppm H2S, carried out in non-commercial supported Pd–Au/Al2O3 membrane reactor (7–8 ?m selective layer thickness) at 823 K and 150 kPa over Rh(1%)/MgAl2O4/Al2O3 catalyst. system is able to recover almost 80% total hydrogen produced during reaction shows good resistance H2S contamination, as confirmed by stable methane conversions for more than 400 h under operation. For comparison, same was commercial self-supported Pd–Ag (150 wall thickness), yielding recovery equal 40% 623 kPa, presenting less operation due effect contamination.

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ژورنال

عنوان ژورنال: International Journal of Hydrogen Energy

سال: 2021

ISSN: ['0360-3199', '1879-3487']

DOI: https://doi.org/10.1016/j.ijhydene.2020.10.038